Proceedings of the DGMK-Conference

"Synthesis Gas Chemistry"

September 27-29, 2000, Dresden, Germany
ISBN 3-931850-69-2


CONTENTS
                                                                                                         Page
Hydroformylation, a success story of homogeneous catalysis
W. A. Herrmann
7
What markets today and tomorrow for synthesis gas ?
P.-R. Bauquis
9
Syngas Chemistry - A link between oil refining and petrochemistry
H.-J. Derdulla, C. Gueguen
23
Low cost production of hydrogen, carbon monoxide and synthesis gas
S. Michel
31
Shell Gasification Process - the most advanced process for converting refinery residues into hydrogen, oxo-gas and power
S. Fritsch, J. Wolff
43
Synthesis gas by direct oxidation of methane in a catalytic
heat-exchange reactor
U. Friedle, J. Schicks, G. Veser
53
Synthesis of methanol
T. Fitzpatrick
61
A new generation of methanol synthesis catalyst
N. Ringer
63
Ca-promoted Pd/SiO2 Catalysts for the synthesis of methanol from synthesis gas: The migration of the promoter
A. F. Gusovius, R. Prins
73
Advances in the cobalt catalyzed Fischer-Tropsch synthesis
P. J. van Berge, S. Barradas, J. van de Loosdrecht, J. L. Visagie
81
Probing the minimum required ensemble size in the ruthenium catalysed Fischer-Tropsch synthesis
M. Claeys, M. Hearshaw-Timme, J. R. Moss, E. van Steen
95
Study of the activation of supported cobalt catalyst for 
Fischer-Tropsch synthesis
M. Roy, M.-C. Marion, J. Lynch, O. Ducreux, F. Hugues
103
Examination of nitrogen diluted syn-gas feeds for Fischer-Tropsch synthesis: microreactor and in situ powder X-ray diffraction study
R. P. K. Wells, P. J. Collier, M. Johns, G. J. Hutchings
111
Status and future aspects of industrial hydroformylation
G. Protzmann, K.-D. Wiese
119
Olefine hydroformylation using classical homogeneous rhodium catalysts
F. A. Kirk
131
Hydroformylation research at BASF
R. Paciello
137
Hydroformylation of higher alkenes: Two-phase catalysis 
or Ligand immobilization?
J. N. H. Reek, Albertus, J. Sandee, M. Schreuder Goedheijt,
P. C. J. Kamer, P. W. N. M. van Leeuwen
145
Water-soluble catalysts for hydroformylation of higher a -olefins
S. Bischoff, M. Kant
157
Homogeneous catalytic carbonylation in supercritical carbon dioxide
W. Leitner
165

POSTERSESSION
 
Some refuting evidence for the alkenyl mechanism as the
main reaction pathway for chain growth in the Fischer-Tropsch synthesis
S. B. Ndlovu, N. S. Phala, M. Hearshaw, P. Beagly, J. R. Moss,
M. Claeys, E. van Steen
171
Factors in synthesis gas production
J. Laege
179
Some news about well-known Co/SiO2 Fischer-Tropsch catalysts
A. L. Lapidus, A. Yu. Krylova
181
Syngas production by steam reforming of natural gas in an autothermal countercurrent reactor
J. Frauhammer, G. Kolios, G. Eigenberger
189
Synthetic fuel and lubricants production using gas-to-liquids technology
M. O. Haid, P. F. Schubert, C. A. Bayens
205
On the way to highly n-regioselective and effective rhodium-catalyzed hydroformylation of internal olefins
D. Selent, D. Hess, D. Röttger, K.-D. Wiese, A. Börner
213
Oxidative carbonylation of phenol
A. L. Lapidus, V. V. Sukhov, O.L. Eliseev
221
Arenes synthesis from CO and H2 over Co-catalysts
A. L. Lapidus, A. Yu. Krylova, A. A. Dergachev, M. V. Krylova
227
Fischer-Tropsch synthesis in a three phase slurry reactor -behaviour of CO2
T. Riedel, D. Unruh, G. Schaub
231
Asymmetric hydroformylations using modified Rhodium/BINAP-catalysts
A. Köckritz, M. Kant, S. Bischoff, R. Siefken, E. Gründemann
239
Rhodium-catalysed hydroformylation in supercritical CO2
substrate structure and reactivity
H. Stemmer, W. Leitner
247