Proceedings of the DGMK-Conference

"Selective Oxidations in Petrochemistry"

October 8 - 9, 1998, Hamburg-Reinbek, Germany
ISBN 3-931850-44-7

CONTENTS
 
  Page
New Vistas in Selective Oxidations
R. Sheldon
7
Selective catalytic oxidations of alkylaromatic compounds
R.W. Fischer and F. Röhrscheid
9
Process engineering in selective alkane oxidations
J.J. Lerou
27
Partial Oxidation of n- and i-pentane over promoted Vanadium-Phosphorus oxide catalysts
V.A. Zazhigalov, B.D. Mikhajluk and G.A. Komashko
29
Active Catalytic Sites in the Ammoxidation of Propane and Propene over V-Sb-O Catalysts
S. A. Buchholz and H. W. Zanthoff
37
A New Kinetic Model Based on the Remote Control Mechanism to Fit Experimental Data in the Selective Oxidation of Propene into Acrolein on bipahsic Catalysts
H. M. Abdeldayem, P. Ruiz, F. C. Thyrion and B. Delmon
45
The liquid phase oxidation of n-Butane: A Search for Plausible Mechanisms
C.C. Hobbs
53
Modelling of the Partial Oxidation of a ,b -unsaturated Aldehydes on Mo-V-Oxides Based Catalysts
H. Böhnke, J.C. Petzoldt, B. Stein, C. Weimer and J. W. Gaube
65
The Morphological Modification of Electrolytic Silver During the OCM Reaction and it´s Effect on Catalysis
A. J. Nagy, G. Weinberg, E. Kitzelmann and G. Mestl
73
Strategies for Catalyst Development: Possibilities of the "Rational approach" illustrated with partial oxidation reactions
W. Weiss, Th. Schedel-Niedrig and R. Schlögl
81
A Predictive Tool for Selective Oxidation of Hydrocarbons: Optical Basicity of Catalysts
P. Moriceau, A. Lebouteiller, E. Bordes and P. Courtine
95
Comparison of the Redox Activities of Sol-Gel and Conventionally Prepared Bi-Mo-Ti Mixed Oxides
M. Wildberger, J.-D. Grundwaldt, T. Mallat and A. Baiker
103
Catalytic Oxidative Conversion of Alkanes to Olefins and Oxygenates
M. Baerns
111
Heterogeneous Catalytic Oxidative dehydrogenation of ethylbenzene to Styrene with Carbon Dioxide
T. Badstube, H. Papp, P. Kustrowski and R. Dziembaj
125
V2O5-ZrO2 catalysts for the oxidative dehydrogenation of propane – Influence of the niobium oxide doping
S. Albrecht, K.-H. Hallmeier, G. Wendt and G. Lippold
131
Postersession  
   
Oxidative Dehydrogenation of Ethane on Rare-Earth Oxide-Based Catalysts
O. Buyevskaya and M. Baerns
139
Selective Epoxidation of Allylic Alcohols with a Titania-Silica Aerogel
M. Dusi, T. Mallat and A. Baiker
147
The Silver Catalyst Process for Converting Methanol to Formaldeyhde - Kinetic Investigations
E. Panzer and G. Emig
155
Phenol by Direct Hydroxylation of Benzene with Nitrous Oxide - Role of surface Oxygen Species in the Reaction Pathways
A. Reitzmann, E. Klemm, G. Emig, S. A. Buchholz and H. W. Zanthoff
163
Partial Oxidation of n-Butane to maleic Anhydride over a Vanadiumpyrophosphate Catalyst in the Riser Regenerator System
St. Heß, M. Liauw and G. Emig
171
Oxidation of aromatic Alcohols on Zeolite-Encapsulated Copper Amino Acid Complexes
S. Ernst and J. M. Teixeira Florêncio
173
a -Sb204 - Induced Improvements of the catalytic behavior of MoO3-(010) in the oxygen-assisted dehydration of 2-butanol: Implications in selective oxidation
E. M. Gaigneaux, M.-L. Naeye, O. Dupont, M. Callant, B. Kartheuser,
P. Ruiz and B. Delmon
181
Selective Oxidations on Vanadiumoxide Containing Amorphous Mixed Oxides (AMM-V) with Tert.-Butylhydroperoxide
Y. Deng, M. Hunnius, S. Storck and W. F. Maier
191
On the catalytic gas phase oxidation of butadiene to furan
B. Kubias, U. Rodemerck, F. Ritschl and M. Meisel
201
Supercritical Carbon Dioxide as an Innovative Reaction Medium for Selective Oxidation
F. Loeker and W. Leitner
209
Characterization of VPO Ammoxidation Catalysts by in situ Methods
A. Martin, B. Lücke, A. Brückner, U. Steinike, K.-W. Brzezinka and M. Meisel
217
Partial Oxidation of 2-Propanol on Perovskites
R. Sumathi, B. Viswanathan and T. K. Varadarajan
225
Chemo-enzymatic Epoxidation of Olefins by Carboxylic Acid Esters and Hydrogen Peroxide
M. Rüsch gen. Klaas and S. Warwel
233
Study of Propane Partial Oxidation on Vanadium-Containing Catalysts
G. A. Komashko, S. V. Khalamejda and V. A. Zazhigalov
241
Active Groups for Oxidative Activation of C-H Bond in C2-C5 Paraffins on V-P-O Catalysts
V. A. Zazhigalov
249
Adsorption and Reaction on a Polar Single Crystalline Chromia Surface
O. Seiferth, M. Bender, B. Dillmann, D. Ehrlich, I. Hemmerich,
F. Rohr, K. Wolter, C. Xu, H. Kuhlenbeck and H.-J. Freund
257