Proceedings of the DGMK-Conference

"Synthesis Gas Chemistry"

     October 4 - 6, 2006, Dresden, Germany

                    ISBN 3-936418-57-8


CONTENTS

 

Page

Overview of Syngas Generation from Different Sources and Main Pathways for Syngas Conversion
T. Fleisch  (Presentation)

7

 

 

The Lurgi MegaMethanol Technology – Delivering the Building Blocks for the Future Fuel and Monomer Demand
T. Wurzel   (Presentation)

9

 

 

Real Condition High Throughput Screening of CuO/ZnO/Al2O3 Catalysts for Methanol Synthesis
C. Baltes, S. Vukojević, F. Schüth (Abstract)

19

 

 

Cu/ZnOx Colloids as Catalysts for Liquid Phase Methanol Synthesis
L. Khodeir, S. J. Miao, E. Löffler, M. Muhler, M. K. Schröter,
R. A. Fischer (Abstract)

27

 

 

From Syngas to Products
R. Fischer

31

 

 

New Catalysts and New Synthetic Applications for Hydroformylation
B. Breit

33

 

 

Novel Reaction Engineering Concepts for Catalyst Immobilisation in Hydroformylation
D. J. Cole-Hamilton, S. L. Desset, U. Hintermair,
C. C. Santini, M. J. Muldoon (Presentation)

41

 

 

High Pressure Hydroformylation in the Chemical Industry
R. Paciello

53

 

 

SILP Catalysis in Gas-Phase Hydroformylation and Carbonylation
A. Riisager, R. Fehrmann, M. Haumann, P. Wasserscheid
(Presentation)

57

 

 

Ligand Modifications for Mono- and Biphasic Oxosynthesis
P. Härter, W. A. Herrmann, D. Baskakov

65

 

 

Hydroformylation of Olefins with Cobalt/Phosphonate- and Cobalt/Sulfonate-Phosphines
A. Martin, M. Kant, G. Giuffrida, S. Rosano  (Abstract)

67

 

 

Fischer-Tropsch Synthesis - Development and Perspectives
G. Schaub, M. Rohde, A. Mena Subiranas

75

 


Principles of Selectivity in Fischer-Tropsch Synthesis
H. Schulz

85

 

 

Fischer-Tropsch Synthesis on Supported Iron Crystallites of Different Size
E. I. Mabaso, E. van Stehen, M. Claeys

93

 

 

The ENI/IFP-Axens GTL Technology: From R&D to a Successful Scale-Up
R. Zennaro, F. Hugues, E. Caprani (Presentation)

101

 

 

Prediction of Vapour-Liquid Equilibria for the Kinetic Study of Processes Based on Synthesis Gas
M. Di Serio, R. Tesser, M. Cozzolino, E. Santacesaria (Abstract)

109

 

 

Comprehensive Characterisation of Products from Cobalt Catalysed Fischer-Tropsch Reaction
M.-C. Marion, F. Bertoncini, F. Hugues, A. Forestière (Abstract)

117

 

 

Kinetic Modeling of the Fischer-Tropsch Synthesis
C. Gambaro, L. Lietti, E. Tronconi, P. Pollesel, R. Zennaro (Abstract)

127

 

 

Syngas from Biomass – Problems and Solutions en Route to a Technical Realisation
E. Dinjus, N. Dahmen, E. Henrich (Presentation)

135

 

 

Selective Catalytic Conversion of Ethanol to Basic Chemicals over Phosphorus-Modified H-ZSM-5 Zeolites
N. Danilina, H. Toufar, W. Reschetilowski (Abstract)

141

 

 

Hydrogen Production by Aqueous-Phase Reforming of Glycerol on Supported Nobel Metal Catalysts
A. Boonyanuwat, A. Jentys, J. A. Lercher (Abstract)

The Shell GTL Process: Towards a World Scale Project in Qatar       (no manuscript available)
A. Hoek (Presentation)

149

 Postersession:

Fischer-Tropsch Synthesis in a Two Phase Reactor with
Presaturation

W. Wache, L. Datsevich, A. Jess

157

 

 

Microreactor Concepts for Enhanced Mass Transfer in the Two-Phase Hydroformylation of 1-Octene
E. Dietzsch, J. Müller, N. Völkel, E. Klemm  (Abstract)

163

 

 

Precious Metal Compounds and Recovery: Fischer-Tropsch Catalysts and Catalysts for Hydroformylation and Oxo Processes
J. Schapp, H. Meyer, M. Arndt (Abstract)

171

 




 

 

Mechanism of Carbon Dioxide Hydrogenation Over Copper and Nickel Catalysts
A. L. Lapidus, N. A. Gaidai, N. V. Nekrasov, L. A. Tishkova,
Yu. A. A. Agafonov, T. N. Myshenkova  (Abstract)

177

 

 

Catalytic Performance of Co/Zeolite in Fischer-Tropsch Synthesis
A. L. Lapidus, O. L. Eliseev, P. E. Davydov, A. S. Volkov (Abstract)

185

 

 

Hydroxycarbonylation of Olefins and Alcohols in Ionic Liquids
A. L. Lapidus, O. L. Eliseev, T. N. Bondarenko, N. N. Stepin (Abstract)

191

 

 

Zeolite Catalysts for Production of Synthetic Highly-Octane Gasoline by Method of Fischer-Tropsch
A. V. Abramova, A. A. Panin, G. A. Kliger, S. N. Khadzhiev  (Abstract)

199

 

 

Conversion of Dimethyl Ether on Zeolite Catalysts
A. V. Abramova, R. V. Kulumbegov, S. N. Khadzhiev (Abstract)

207

 

 

Fischer-Tropsch Synthesis with In-situ H2O Removal by a New Hydrophilic Membrane – An Experimental and Modelling Study
M. P. Rohde, G. Schaub, J. F. Vente, H. M. van Veen

215

 

 

Closing the Gap between Homogeneuous and Heterogeneous Fischer-Tropsch Synthesis
C. Welker, J. R. Moss, E. van Steen, M. Claeys  (Abstract)

223

 

 

Hydroaminomethylation in Supercritical Ammonia
A. Martin, M. Kant, H. Klein, R. Jackstell, M. Beller  (Abstract)

231

 

 

Synthesis Gas/H2 via SCT-CPO: A Pilot-Plant Experience
L. Basini, G. Campanelli, R. Cimino, C. Ficili, A. Guarinoni, R. Ponzo
 (Abstract)

239

 

 

Phospine Modified Cobalt Hydroformylation
H. van Rensburg, W. Janse van Rensburg, R. P. Tooze, D. F. Foster

247

 

 

Development of a Complete Kinetic Model for the Fischer-Tropsch-Synthesis over Co/Al2O3 Catalysts
C. G. Visconti, E. Tronconi, L. Lietti, R. Zennaro, P. Forzatti (Abstract)

255