"Chances for Innovative Processes
at the Interface
between Refining and Petrochemistry"
October 9 - 11, 2002, Berlin, Germany
ISBN 3-931850-98-6
CONTENTS
Page
Light Naphtha Isomerisation To Meet 21st Century Gasoline
7
Specifications
M. J. Hunter
Structural and Active Site Characterization of Sulfated
23
Zirconia Catalysts for Light Alkane Isomerization
M. Standke, C. Breitkopf, H. Papp, S. Wrabetz, B. S. Klose, X. Yang,
R. E. Jentoft, F. C. Jentoft, X. Li, L. J. Simon, J. A. Lercher
Isomerisation of n-pentane over heteropolyacid catalysts:
31
onomolecular versus bimolecular mechanism in relation
with the presence of platinum and hydrogen
N. Essayem, Y. B. Tarit, C. Fèche, P. Y. Gayraud, G. Sapaly,
C. Naccache
Recent Developments in Isobutane/Olefin Alkylation
41
J. A. Lercher, A. Feller
Outlook and perspectives of non-phosgene DMC production
53
F. Rivetti
Alkanes as Substitutes for Alkenes in the Manufacture of
61
Petrochemicals – A Continuing Challenge of the Presence
and the Future
M. Baerns, G. Grubert, E. V. Kondratenko, D. Linke, U. Rodemerck
Maleic Anhydride from Mixtures of n-Butane and n-Butenes
79
W. M. Brandstädter, P. Casaretto, B. Kraushaar-Czarnetzki
Gas phase oxidation of methyl aromatics to their
87
corresponding aldehydes
A. Martin, U. Bentrup, B. Lücke, G.-U. Wolf
Prins Condensation of Isobutylene and Formaldehyde over
95
Isomorphously Substituted Zeolite MCM-22
E. Dumitriu, V. Hulea, A. Auroux, C. Guimon, I. Fechete
Ionic Liquids – A New Concept for Catalysis and
97
Separation Technology
P. Wasserscheid
Room Temperature Ionic Liquids as Solvents for Olefins
107
Dimerization (Difasol process) and Hydroformylation
F. Favre, A. Forestière, F. Hugues, H. Olivier-Bourbigou,
J. A. Chodorge
MaxEneTM process-based low capital petrochemical complex
115
V. Bhirud, T. Foley, P. Pujadó
Improving the Yield of Ethene in the Steamcracker by
123
Recycling of Pyrolysis Gasoline Using Pd-, Pt-, Ir- or
Ga-doped Zeolites ZSM-5
A. Raichle, Y. Traa, F. Fuder, M. Rupp, J. Weitkamp
Catalytic Membrane Reactors: Where do we stand?
131
R. Dittmeyer
Conversion of Aromatic Gasoline Blend Components
147
into p-Xylene
K. Kretschmar, R. Kopetz
New Chances for Innovative Links between Refinery
153
and Petrochemistry at an old Chemical Site
H.-J. Derdulla, W. de Veij
Novel Catalysts for the Isomerization of C5 to C7
Alkanes
161
for Octane-Boosting
M. Hartmann, S. P. Elangovan, M. Gerstner, T. Hecht, S. Ernst
Selective iso-Paraffin Synthesis form CO and H2 over
169
Co Catalysts
A. Krylova, A. Lapidus
Catalytic Distillation – a Powerful Tool for Process Integration
175
G. Kaibel, G. Kons, H. Schoenmakers, E. Schwab
Reactive Separation of Isobutene from C4-fractions using
187
Coupled Reactive Distillation Columns
Z. Qi, K. Sundmacher, E. Stein, A. Kienle
POSTERSESSION
Improved Hydroisomerization Catalysts for Light Alkane
195
Isomerization
L. J. Simon, A. Kinage, J. A. Lercher
Isomerisation of Propadiene to Propyne – Catalyst Screening
203
and Kinetic Measurements
R. Dotzel, E. Klemm
Modification of Pt/Al2O3 catalysts for n-hexane
211
hydroisomerization
A. L. Lapidus, A. A. Dergachev, A. A. Silakova
In-Situ Spectroscopic Study of Isomerization of Light Alkanes
217
over Sulfated Zirconia Catalysts
X. Yang, R. Ahmad, J. Melsheimer, B. Klose, F. C. Jentoft
Copper-Promoted Pt-Catalysts for the Non-Oxidative Propane
225
Dehydrogenation
T. Donauer, R. Gläser, J. Weitkamp
Novel Catalysts for Oxidative Olefin Generation
233
J. Find, S. Gaab, M. Machli, J. A. Lercher
Aromatics Synthesis from Propane over Zeolite-Containing
241
Catalysts
A. Lapidus, A. Dergachev, M. Krylova, I. Maslov, A. Krylova
Side-chain alkylation of toluene with 2-propanol catalyzed
247
by basic zeolites
V. Herzog, J. Münch, W. Schwieger
Zeolite-Catalyzed Methylation of Pyrazole with Dimethyl
255
Carbonate
S. Born, J. Weichert, M. Hartmann, S. Ernst
Structural Effects in MCM-41, Zeolite Y and Active Matrix
263
in Catalytic Cracking Composites
A. Taouli, H. Koch, W. Reschetilowski
Selective oxidation of hydrocarbons in microchannel reactors
271
S. Walter, M. A. Liauw
Partial Oxidation of Cyclohexane in Supercritical Carbon
273
Dioxide
U. Armbruster, A. Martin
Direct Hydroxylation of Benzene to Phenol – Aspects of
277
Catalyst development and reaction kinetics
A. Unger, U. Hiemer, A. Reitzmann, E. Klemm, W. Schwieger
In-situ study of methanol steam reforming on PdZn catalysts
285
F. Kiesslich, P. Prechtl, M. A. Liauw, G. Emig
In-situ Removal of H2O during Fischer-Tropsch Synthesis
–
287
a Modelling Study
D. Unruh, M. Rohde, G. Schaub
Removal of Residual Sulfur Compounds Using Fixed-Bed
295
Adsorption
E. Aust, A. B. Bruccolini
High throughput methods for the identification of new catalysts
301
for hydroisomerization of light n-alkanes
O. M. Busch, St. J. Thomson, F. Schüth